9ST (Grab ST Bobblehead right out of the Vault)
5PE
5EN
1CH
9IN (Grab IN Bobblehead RIGHT out of the Vault)
6AG
5LK

Energy Weapons
Sneak
Small Guns

2-Black Widow (None)
3-Swift Learner (IN 4)
4-Educated (IN 4)
5-Comprehension (IN 4)
6-Bloody Mess (None)
7-Gunslinger (None)
8-Commando (None)
9-Strong Back (ST 5, EN 5)
10-Finesse (None)
11-Mysterious Stranger (LK 6)
12-Sniper (PE 6, AG 6)
13-Silent Running (AG 6, Sneak 50)
14-Cyborg (Medicine 60, Science 60)
15-Pyromaniac (Explosives 60)
16-Action Boy (AG 6)
17-Better Criticals (PE 6, LK 6)
18-Concentrated Fire (Energy Weapons 60, Small Guns 60)
19-Demolition Expert (Explosives 50)
20-Grim Reapers Sprint (None)
21-Ninja (Melee Weapons 80, Sneak 80)
22-Explorer (None)
23-Robotics Expert (Science 50)
24-Paralyzing Palm (Unarmed 70) [If you don't have 70 by this level then take an iron fist and take Paralyzing Palm at a later level (26,28,29)]
25-Demolition Expert, Rank 2 (Explosives 50)
26-Iron Fist (ST 4)
27-Demolition Expert, Rank 3 (Explosives 50)
28-Iron Fist (ST 4)
29-Iron Fist (ST 4)
30-Almost Perfect (None)

Quest Perks:

Before Level 11-Lucky 8 Ball - adds 1 LK for Obtaining Perks (Quest: Big Trouble in BigTown)
Before Level 12-Ant Sight (Quest: Those!)
Before Level 30-Yew Bear's Charm (Quest: Oasis)

Barkskin
Wired Reflexes
Survival Guru
Hematophage
Power Armor Training

DLC Perks:

(Operation Anchorage)Covert Ops
(The Pitt)Pitt Fighter/Booster Shot/Auto Axpert
(Mothership Zeta)Xenotech Expert
(Point Lookout)Ghoul Ecology/Superior Defender/Punga Power

You will need to get all 13 skill Bobbleheads that actually give 10 skill points
You will need Yew's Bear Charm (+10 Speech)
Also you will need to get around 63 skill books

Clothing - Depending on your play style/preference, you can use whatever you want

Stealth:
Body: Chinese Stealth Armor
Hat: Any combination of headgear you want

Action Points:
Body: Lag-Bolt's Combat Armor (+10 AP)
Hat: Ledox's Hockey Mask (+25 AP)
Weapon: Wazer Wifle/Ritual Knife are good for lots of vats shots

Super Defense:
Body: Winterized Power Armor
Hat: Winterized Power Helmet
Weapon: Minigun/Eugene, Flamer/Burnmaster, Gatling Lazer/Vengance